Abstract

The photodesorption kinetics of graphene with various UV laser power is studied by conductance response. Analytical expressions of the power-dependent photodesorption kinetics of graphene in ambience are derived. The photodesorption time constant τd, steady current, and magnitude of modulation current, can be expressed as functions of the adsorption time constant τa, desorption cross section σ, and photon flux density. Under illumination the steady occupation ratio of adsorbed O2 on graphene is equal to τd/τa. It is suggested that the photodesorption of O2 on graphene is attributed the injection of photogenerated hot electrons and is restricted by the density of antibonding states of O2.

© 2015 Optical Society of America

Full Article  |  PDF Article
OSA Recommended Articles
Intrinsic photocurrent characteristics of graphene photodetectors passivated with Al2O3

Chang Goo Kang, Sang Kyung Lee, Sunhee Choe, Young Gon Lee, Chang-Lyoul Lee, and Byoung Hun Lee
Opt. Express 21(20) 23391-23400 (2013)

Polarization dependence of optical pump-induced change of graphene extinction coefficient

Jun Yao, Xin Zhao, Xiao-Qing Yan, Chengmin Gao, Xu-Dong Chen, Wei Xin, Yongsheng Chen, Zhi-Bo Liu, and Jian-Guo Tian
Opt. Mater. Express 5(7) 1550-1559 (2015)

Pulsed-laser-induced desorption from metal surfaces

Peter C. Stair and Eric Weitz
J. Opt. Soc. Am. B 4(2) 255-260 (1987)

References

  • View by:
  • |
  • |
  • |

  1. A. K. Geim, “Graphene: status and prospects,” Science 324(5934), 1530–1534 (2009).
    [Crossref] [PubMed]
  2. F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
    [Crossref] [PubMed]
  3. Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
    [Crossref] [PubMed]
  4. N. Mohanty and V. Berry, “Graphene-based single-bacterium resolution biodevice and DNA transistor: interfacing graphene derivatives with nanoscale and microscale biocomponents,” Nano Lett. 8(12), 4469–4476 (2008).
    [Crossref] [PubMed]
  5. S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
    [Crossref]
  6. Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
    [Crossref] [PubMed]
  7. P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
    [Crossref]
  8. J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
    [Crossref] [PubMed]
  9. R. Franchy, “Surface and bulk photochemistry of solids,” Rep. Prog. Phys. 61(6), 691–753 (1998).
    [Crossref]
  10. R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
    [Crossref]
  11. S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
    [Crossref]
  12. K. F. Mak, J. Shan, and T. F. Heinz, “Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons,” Phys. Rev. Lett. 106(4), 046401 (2011).
    [Crossref] [PubMed]
  13. D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
    [Crossref] [PubMed]
  14. A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
    [Crossref] [PubMed]
  15. L. W. Bruch, M. W. Cole, and E. Zaremba, Physical Adsorption: Forces and Phenomena (Dover Publications, New York, 2007).
  16. P. D. Cooper, R. E. Johnson, and T. I. Quickenden, “A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies,” Planet. Space Sci. 51(3), 183–192 (2003).
    [Crossref]
  17. P. R. Antoniewicz, “Model for electron- and photon-stimulated desorption,” Phys. Rev. B 21(9), 3811–3815 (1980).
    [Crossref]
  18. R. E. Palmer and P. J. Rous, “Resonances in electron scattering by molecules on surfaces,” Rev. Mod. Phys. 64(2), 383–440 (1992).
    [Crossref]
  19. J. W. Gadzuk, “Excitation mechanisms in vibrational spectroscopy of molecules on surfaces,” in Vibrational Spectroscopy of Molecules on Surfaces, J. T. Yates, Jr., and T. E. Madey, ed. (Springer, New York, 1987).
  20. K. K. Irikura, “Experimental vibrational zero-point energies: diatomic molecules,” J. Phys. Chem. Ref. Data 36(2), 389–397 (2007).
    [Crossref]
  21. P. Giannozi, R. Car, and G. Scoles, “Oxygen adsorption on graphite and nanotubes,” J. Chem. Phys. 118(3), 1003–1006 (2003).
    [Crossref]

2013 (1)

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

2012 (1)

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

2011 (3)

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

K. F. Mak, J. Shan, and T. F. Heinz, “Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons,” Phys. Rev. Lett. 106(4), 046401 (2011).
[Crossref] [PubMed]

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

2009 (3)

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

A. K. Geim, “Graphene: status and prospects,” Science 324(5934), 1530–1534 (2009).
[Crossref] [PubMed]

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

2008 (2)

N. Mohanty and V. Berry, “Graphene-based single-bacterium resolution biodevice and DNA transistor: interfacing graphene derivatives with nanoscale and microscale biocomponents,” Nano Lett. 8(12), 4469–4476 (2008).
[Crossref] [PubMed]

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

2007 (2)

K. K. Irikura, “Experimental vibrational zero-point energies: diatomic molecules,” J. Phys. Chem. Ref. Data 36(2), 389–397 (2007).
[Crossref]

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

2003 (2)

P. Giannozi, R. Car, and G. Scoles, “Oxygen adsorption on graphite and nanotubes,” J. Chem. Phys. 118(3), 1003–1006 (2003).
[Crossref]

P. D. Cooper, R. E. Johnson, and T. I. Quickenden, “A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies,” Planet. Space Sci. 51(3), 183–192 (2003).
[Crossref]

2001 (1)

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

2000 (1)

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

1998 (1)

R. Franchy, “Surface and bulk photochemistry of solids,” Rep. Prog. Phys. 61(6), 691–753 (1998).
[Crossref]

1992 (1)

R. E. Palmer and P. J. Rous, “Resonances in electron scattering by molecules on surfaces,” Rev. Mod. Phys. 64(2), 383–440 (1992).
[Crossref]

1980 (1)

P. R. Antoniewicz, “Model for electron- and photon-stimulated desorption,” Phys. Rev. B 21(9), 3811–3815 (1980).
[Crossref]

Achiba, Y.

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

Antoniewicz, P. R.

P. R. Antoniewicz, “Model for electron- and photon-stimulated desorption,” Phys. Rev. B 21(9), 3811–3815 (1980).
[Crossref]

Aoki, K.

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

Berry, V.

N. Mohanty and V. Berry, “Graphene-based single-bacterium resolution biodevice and DNA transistor: interfacing graphene derivatives with nanoscale and microscale biocomponents,” Nano Lett. 8(12), 4469–4476 (2008).
[Crossref] [PubMed]

Blake, P.

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Cao, J.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Car, R.

P. Giannozi, R. Car, and G. Scoles, “Oxygen adsorption on graphite and nanotubes,” J. Chem. Phys. 118(3), 1003–1006 (2003).
[Crossref]

Chae, D.-H.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Chakraborty, B.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Chen, G.

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

Chen, R. J.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Cheng, Y.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Cole, M. W.

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

Cooper, P. D.

P. D. Cooper, R. E. Johnson, and T. I. Quickenden, “A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies,” Planet. Space Sci. 51(3), 183–192 (2003).
[Crossref]

Dai, H.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Dan, Y.

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

Das, A.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Fang, W.

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

Ferrari, A. C.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Franchy, R.

R. Franchy, “Surface and bulk photochemistry of solids,” Rep. Prog. Phys. 61(6), 691–753 (1998).
[Crossref]

Franklin, N. R.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Geim, A. K.

A. K. Geim, “Graphene: status and prospects,” Science 324(5934), 1530–1534 (2009).
[Crossref] [PubMed]

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Giannozi, P.

P. Giannozi, R. Car, and G. Scoles, “Oxygen adsorption on graphite and nanotubes,” J. Chem. Phys. 118(3), 1003–1006 (2003).
[Crossref]

Giessen, H.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Harutyunyan, A. R.

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

Heinz, T. F.

K. F. Mak, J. Shan, and T. F. Heinz, “Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons,” Phys. Rev. Lett. 106(4), 046401 (2011).
[Crossref] [PubMed]

Hill, E. W.

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Irikura, K. K.

K. K. Irikura, “Experimental vibrational zero-point energies: diatomic molecules,” J. Phys. Chem. Ref. Data 36(2), 389–397 (2007).
[Crossref]

Johnson, A. T. C.

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

Johnson, R. E.

P. D. Cooper, R. E. Johnson, and T. I. Quickenden, “A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies,” Planet. Space Sci. 51(3), 183–192 (2003).
[Crossref]

Kataura, H.

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

Katsnelson, M. I.

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Kazaoui, S.

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

Klitzing, K. V.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Kong, J.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Krishnamurthy, H. R.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Kybert, N. J.

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

Kyle, J. R.

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Li, L. J.

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

Liang, S.-Z.

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

Lin, J.

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Lippitz, M.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Lu, Y.

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

Luo, Z.

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

Mak, K. F.

K. F. Mak, J. Shan, and T. F. Heinz, “Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons,” Phys. Rev. Lett. 106(4), 046401 (2011).
[Crossref] [PubMed]

Minami, N.

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

Mohanty, N.

N. Mohanty and V. Berry, “Graphene-based single-bacterium resolution biodevice and DNA transistor: interfacing graphene derivatives with nanoscale and microscale biocomponents,” Nano Lett. 8(12), 4469–4476 (2008).
[Crossref] [PubMed]

Morozov, S. V.

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Novoselov, K. S.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Ozkan, C. S.

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Ozkan, M.

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Palmer, R. E.

R. E. Palmer and P. J. Rous, “Resonances in electron scattering by molecules on surfaces,” Rev. Mod. Phys. 64(2), 383–440 (1992).
[Crossref]

Penchev, M.

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Pisana, S.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Piscanec, S.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Quickenden, T. I.

P. D. Cooper, R. E. Johnson, and T. I. Quickenden, “A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies,” Planet. Space Sci. 51(3), 183–192 (2003).
[Crossref]

Rous, P. J.

R. E. Palmer and P. J. Rous, “Resonances in electron scattering by molecules on surfaces,” Rev. Mod. Phys. 64(2), 383–440 (1992).
[Crossref]

Saha, S. K.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Schedin, F.

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Scoles, G.

P. Giannozi, R. Car, and G. Scoles, “Oxygen adsorption on graphite and nanotubes,” J. Chem. Phys. 118(3), 1003–1006 (2003).
[Crossref]

Shan, J.

K. F. Mak, J. Shan, and T. F. Heinz, “Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons,” Phys. Rev. Lett. 106(4), 046401 (2011).
[Crossref] [PubMed]

Shi, Y.

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

Smet, J.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Sofo, J. O.

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

Sood, A. K.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Sun, P.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Tombler, T. W.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Utikal, T.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Waghmare, U. V.

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Wang, K.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Wei, J.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Weisenburger, S.

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Wu, D.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Yamawaki, H.

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

Zhang, K.

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

Zhang, W.

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

Zhang, Y.

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

Zhong, J.

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Zhong, M.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Zhu, H.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Zhu, M.

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

Appl. Phys. Lett. (3)

S.-Z. Liang, G. Chen, A. R. Harutyunyan, M. W. Cole, and J. O. Sofo, “Analysis and optimization of carbon nanotubes and graphene sensors based on adsorption-desorption kinetics,” Appl. Phys. Lett. 103(23), 233108 (2013).
[Crossref]

P. Sun, M. Zhu, K. Wang, M. Zhong, J. Wei, D. Wu, Y. Cheng, and H. Zhu, “Photoinduced molecular desorption from graphene films,” Appl. Phys. Lett. 101(5), 053107 (2012).
[Crossref]

R. J. Chen, N. R. Franklin, J. Kong, J. Cao, T. W. Tombler, Y. Zhang, and H. Dai, “Molecular photodesorption from single-walled carbon nanotubes,” Appl. Phys. Lett. 79(14), 2258–2260 (2001).
[Crossref]

J. Chem. Phys. (1)

P. Giannozi, R. Car, and G. Scoles, “Oxygen adsorption on graphite and nanotubes,” J. Chem. Phys. 118(3), 1003–1006 (2003).
[Crossref]

J. Phys. Chem. Ref. Data (1)

K. K. Irikura, “Experimental vibrational zero-point energies: diatomic molecules,” J. Phys. Chem. Ref. Data 36(2), 389–397 (2007).
[Crossref]

Nano Lett. (3)

D.-H. Chae, T. Utikal, S. Weisenburger, H. Giessen, K. V. Klitzing, M. Lippitz, and J. Smet, “Excitonic Fano resonance in free-standing graphene,” Nano Lett. 11(3), 1379–1382 (2011).
[Crossref] [PubMed]

Y. Dan, Y. Lu, N. J. Kybert, Z. Luo, and A. T. C. Johnson, “Intrinsic response of graphene vapor sensors,” Nano Lett. 9(4), 1472–1475 (2009).
[Crossref] [PubMed]

N. Mohanty and V. Berry, “Graphene-based single-bacterium resolution biodevice and DNA transistor: interfacing graphene derivatives with nanoscale and microscale biocomponents,” Nano Lett. 8(12), 4469–4476 (2008).
[Crossref] [PubMed]

Nanotechnology (1)

J. Lin, J. Zhong, J. R. Kyle, M. Penchev, M. Ozkan, and C. S. Ozkan, “Molecular absorption and photodesorption in pristine and functionalized large-area graphene layers,” Nanotechnology 22(35), 355701 (2011).
[Crossref] [PubMed]

Nat. Mater. (1)

F. Schedin, A. K. Geim, S. V. Morozov, E. W. Hill, P. Blake, M. I. Katsnelson, and K. S. Novoselov, “Detection of individual gas molecules adsorbed on graphene,” Nat. Mater. 6(9), 652–655 (2007).
[Crossref] [PubMed]

Nat. Nanotechnol. (1)

A. Das, S. Pisana, B. Chakraborty, S. Piscanec, S. K. Saha, U. V. Waghmare, K. S. Novoselov, H. R. Krishnamurthy, A. K. Geim, A. C. Ferrari, and A. K. Sood, “Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor,” Nat. Nanotechnol. 3(4), 210–215 (2008).
[Crossref] [PubMed]

Phys. Rev. B (2)

S. Kazaoui, N. Minami, H. Yamawaki, K. Aoki, H. Kataura, and Y. Achiba, “Pressure dependence of the optical absorption spectra of single-walled carbon nanotubes films,” Phys. Rev. B 62(3), 1643–1646 (2000).
[Crossref]

P. R. Antoniewicz, “Model for electron- and photon-stimulated desorption,” Phys. Rev. B 21(9), 3811–3815 (1980).
[Crossref]

Phys. Rev. Lett. (1)

K. F. Mak, J. Shan, and T. F. Heinz, “Seeing many-body effects in single- and few-layer graphene: observation of two-dimensional saddle-point excitons,” Phys. Rev. Lett. 106(4), 046401 (2011).
[Crossref] [PubMed]

Planet. Space Sci. (1)

P. D. Cooper, R. E. Johnson, and T. I. Quickenden, “A review of possible optical absorption features of oxygen molecules in the icy surfaces of outer solar system bodies,” Planet. Space Sci. 51(3), 183–192 (2003).
[Crossref]

Rep. Prog. Phys. (1)

R. Franchy, “Surface and bulk photochemistry of solids,” Rep. Prog. Phys. 61(6), 691–753 (1998).
[Crossref]

Rev. Mod. Phys. (1)

R. E. Palmer and P. J. Rous, “Resonances in electron scattering by molecules on surfaces,” Rev. Mod. Phys. 64(2), 383–440 (1992).
[Crossref]

Science (1)

A. K. Geim, “Graphene: status and prospects,” Science 324(5934), 1530–1534 (2009).
[Crossref] [PubMed]

Small (1)

Y. Shi, W. Fang, K. Zhang, W. Zhang, and L. J. Li, “Photoelectrical response in single-layer graphene transistors,” Small 5(17), 2005–2011 (2009).
[Crossref] [PubMed]

Other (2)

J. W. Gadzuk, “Excitation mechanisms in vibrational spectroscopy of molecules on surfaces,” in Vibrational Spectroscopy of Molecules on Surfaces, J. T. Yates, Jr., and T. E. Madey, ed. (Springer, New York, 1987).

L. W. Bruch, M. W. Cole, and E. Zaremba, Physical Adsorption: Forces and Phenomena (Dover Publications, New York, 2007).

Cited By

OSA participates in Crossref's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Figures (5)

Fig. 1
Fig. 1 (a) Response current of graphene on photodesorption with various UV power densities, and (b) Raman spectra of adsorbed and desorbed graphenes.
Fig. 2
Fig. 2 Photodesorption time constant τd (as well as Ns/Nmax referring to the second ordinate on the left hand side) and ΔI (as well as ΔN/Nmax referring to the second ordinate on the right side) as functions of the photon flux density (and power density). The solid line are the fittings from Eqs. (7) and (8).
Fig. 3
Fig. 3 Dependence of Is and ΔI on τd.
Fig. 4
Fig. 4 Dependence of cross section σ of graphene on photon energy, including the cross section σ of single-walled CNTs by 254 nm UV light [10].
Fig. 5
Fig. 5 (a) Photodesorption mechanism of graphene: (from left to right) excitation of electrons by the optical absorption of graphene, electron tunneling from graphene to the antibonding orbital of O2, and O2 acquires kinetic energy to desorb via the Franck-Condon transition. (b) Schematic of the vibronic levels of O2 and O 2 to illustrate the Franck-Condon transition.

Equations (13)

Equations on this page are rendered with MathJax. Learn more.

d N ( t ) d t = σ F N ( t ) ,
I ( t ) = I s + Δ I e t / τ d ,
I ( t ) = I 0 Δ I e t / τ a ,
d N ( t ) d t = τ a 1 ( N max N ( t ) ) .
d N ( t ) d t = τ a 1 ( N max N ( t ) ) σ F N ( t ) .
N ( t ) = N max ( τ a 1 τ a 1 + σ F ) + N max ( σ F τ a 1 + σ F ) e ( τ a 1 + σ F ) t ,
τ d = ( τ a 1 + σ F ) 1 ,
Δ I = I N max σ F τ a 1 + σ F , a n d
I s = I N max τ a 1 τ a 1 + σ F + I i .
Δ I = I N max ( 1 τ d τ a ) , a n d
I s = I N max τ d τ a + I i ,
N s N max = I s I i I 0 I i , a n d Δ N N max = Δ I I 0 I i .
N s N max = τ d τ a , a n d Δ N N max = 1 τ d τ a .

Metrics