Abstract

A highly sensitive technique for analyzing surface tension and dynamic viscosity of nanofluids was reported. Multiwall carbon nanotubes suspended in ethanol were evaluated. The assistance of a Fabry-Perot interferometer integrated by a small sample volume fluid allowed us to explore the stability and mechanical properties exhibited by the nanostructures. The surface tension and dynamic viscosity of the colloid was examined by using interferometric optical signals reflected from a remnant drop pending at the end of an optical fiber. Nanosecond pulses provided by a Nd:YAG laser source with 9.5 MW/mm2 at 532 nm wavelength were used to induce mechano-optical effects in the liquid drop. The mechanical parameters were approximated, taking into account single optical pulses interacting with an inelastic mass-spring-damper system.

© 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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References

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2017 (4)

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

A. Karthikeyan, S. Coulombe, and A. M. Kietzig, “Wetting behavior of multi-walled carbon nanotube nanofluids,” Nanotechnology 28(10), 105706 (2017).
[Crossref] [PubMed]

K. Akulov and T. Schwartz, “Picosecond optomechanical oscillations in metal-polymer microcavities,” Opt. Lett. 42(13), 2411–2414 (2017).
[Crossref] [PubMed]

2016 (2)

D. Winarto, D. Takaiwa, E. Yamamoto, and K. Yasuoka, “Separation of water-ethanol solutions with carbon nanotubes and electric fields,” Phys. Chem. Chem. Phys. 18(48), 33310–33319 (2016).
[Crossref] [PubMed]

J. A. Carlos-Cornelio, P. Andre-Cuervo, L. M. Hoyos-Palacios, J. Lara-Romero, and A. Toro, “Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system,” J. Mater. Res. Technol. 5(1), 68–76 (2016).
[Crossref]

2015 (2)

J. A. García-Merino, C. L. Martínez-González, C. R. Torres-San Miguel, M. Trejo-Valdez, H. Martínez-Gutiérrez, and C. Torres-Torres, “Photothermal, photoconductive and nonlinear optical effects induced by nanosecond pulse irradiation in multi-wall carbon nanotubes,” Mater. Sci. Eng. B 194, 27–33 (2015).
[Crossref]

C. Liu, Y. Tanaka, and Y. Fujimoto, “Viscosity transient phenomenon during drop testing and its simple dynamics model,” World J. Mech. 5(03), 33–41 (2015).
[Crossref]

2014 (2)

2013 (2)

E. Feria-Reyes, C. Torres-Torres, H. Martínez-Gutiérrez, S. Morales-Bonilla, R. Torres-Martínez, M. Trejo-Valdez, and G. Urriolagoitia-Calderón, “Mechano-optical modulation and optical limiting by multiwall carbon nanotubes,” J. Mod. Opt. 60(16), 1321–1326 (2013).
[Crossref]

C. Torres-Torres, N. Peréa-López, H. Martínez-Gutiérrez, M. Trejo-Valdez, J. Ortíz-López, and M. Terrones, “Optoelectronic modulation by multi-wall carbon nanotubes,” Nanotechnology 24(4), 045201 (2013).
[Crossref] [PubMed]

2012 (1)

D. Nikolić and L. Nesic, “Determination of surface tension coefficient of liquids by diffraction of light on capillary waves,” Eur. J. Phys. 33(6), 1677–1685 (2012).
[Crossref]

2011 (1)

R. H. Chen, T. X. Phuoc, and D. Martello, “Surface tension of evaporating nano〉uid droplets,” Int. J. Heat Mass Transfer 54(11–12), 2459–2466 (2011).
[Crossref]

2010 (1)

D. A. Fletcher and R. D. Mullins, “Cell mechanics and the cytoskeleton,” Nature 463(7280), 485–492 (2010).
[Crossref] [PubMed]

2009 (2)

R. Rajasekharan-Unnithan, H. Butt, and T. D. Wilkinson, “Optical phase modulation using a hybrid carbon nanotube-liquid-crystal nanophotonic device,” Opt. Lett. 34(8), 1237–1239 (2009).
[Crossref] [PubMed]

G. R. Vakili-Nezhaad and A. Dorany, “Investigation of the Effect of Multiwalled Carbon Nanotubes on the Viscosity Index of Lube Oil Cuts,” Chem. Eng. Comm. 196(9), 997–1007 (2009).

2006 (1)

T. Chen, M. S. Chiu, and C. N. Weng, “Derivation of the generalized Young-Laplace equation of curved interfaces in nanoscaled solidsm,” J. Appl. Phys. 100(7), 074308 (2006).
[Crossref]

2001 (1)

J. Maultzsch, S. Reich, and C. Thomsen, “Chirality-selective Raman scattering of the D mode in carbon nanotubes,” Phys. Rev. B Condens. Matter 64(12), 121407 (2001).
[Crossref]

1993 (1)

K. D. O’Hare, P. L. Spedding, and J. Grimshaw, “Evaporation of the ethanol and water components comprising a binary liquid mixture,” Asia-Pac. J. Chem. Eng. 1(2–3), 118–128 (1993).

1985 (1)

Akulov, K.

Andre-Cuervo, P.

J. A. Carlos-Cornelio, P. Andre-Cuervo, L. M. Hoyos-Palacios, J. Lara-Romero, and A. Toro, “Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system,” J. Mater. Res. Technol. 5(1), 68–76 (2016).
[Crossref]

Bain, C. D.

Barland, S.

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

Bhat, A.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Blick, R.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Butt, H.

Carlos-Cornelio, J. A.

J. A. Carlos-Cornelio, P. Andre-Cuervo, L. M. Hoyos-Palacios, J. Lara-Romero, and A. Toro, “Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system,” J. Mater. Res. Technol. 5(1), 68–76 (2016).
[Crossref]

Chakrabarti, B.

Chen, R. H.

R. H. Chen, T. X. Phuoc, and D. Martello, “Surface tension of evaporating nano〉uid droplets,” Int. J. Heat Mass Transfer 54(11–12), 2459–2466 (2011).
[Crossref]

Chen, T.

T. Chen, M. S. Chiu, and C. N. Weng, “Derivation of the generalized Young-Laplace equation of curved interfaces in nanoscaled solidsm,” J. Appl. Phys. 100(7), 074308 (2006).
[Crossref]

Chiu, M. S.

T. Chen, M. S. Chiu, and C. N. Weng, “Derivation of the generalized Young-Laplace equation of curved interfaces in nanoscaled solidsm,” J. Appl. Phys. 100(7), 074308 (2006).
[Crossref]

Coen, S.

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

Coulombe, S.

A. Karthikeyan, S. Coulombe, and A. M. Kietzig, “Wetting behavior of multi-walled carbon nanotube nanofluids,” Nanotechnology 28(10), 105706 (2017).
[Crossref] [PubMed]

Diaz-Rivera, R. E.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Dorany, A.

G. R. Vakili-Nezhaad and A. Dorany, “Investigation of the Effect of Multiwalled Carbon Nanotubes on the Viscosity Index of Lube Oil Cuts,” Chem. Eng. Comm. 196(9), 997–1007 (2009).

Erkintalo, M.

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

Feria-Reyes, E.

E. Feria-Reyes, C. Torres-Torres, H. Martínez-Gutiérrez, S. Morales-Bonilla, R. Torres-Martínez, M. Trejo-Valdez, and G. Urriolagoitia-Calderón, “Mechano-optical modulation and optical limiting by multiwall carbon nanotubes,” J. Mod. Opt. 60(16), 1321–1326 (2013).
[Crossref]

Fletcher, D. A.

D. A. Fletcher and R. D. Mullins, “Cell mechanics and the cytoskeleton,” Nature 463(7280), 485–492 (2010).
[Crossref] [PubMed]

Fujimoto, Y.

C. Liu, Y. Tanaka, and Y. Fujimoto, “Viscosity transient phenomenon during drop testing and its simple dynamics model,” World J. Mech. 5(03), 33–41 (2015).
[Crossref]

García-Merino, J. A.

J. A. García-Merino, C. L. Martínez-González, C. R. Torres-San Miguel, M. Trejo-Valdez, H. Martínez-Gutiérrez, and C. Torres-Torres, “Photothermal, photoconductive and nonlinear optical effects induced by nanosecond pulse irradiation in multi-wall carbon nanotubes,” Mater. Sci. Eng. B 194, 27–33 (2015).
[Crossref]

Giudici, M.

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

Grimshaw, J.

K. D. O’Hare, P. L. Spedding, and J. Grimshaw, “Evaporation of the ethanol and water components comprising a binary liquid mixture,” Asia-Pac. J. Chem. Eng. 1(2–3), 118–128 (1993).

Hernández-Cordero, J. A.

Hoyos-Palacios, L. M.

J. A. Carlos-Cornelio, P. Andre-Cuervo, L. M. Hoyos-Palacios, J. Lara-Romero, and A. Toro, “Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system,” J. Mater. Res. Technol. 5(1), 68–76 (2016).
[Crossref]

Javaloyes, J.

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

Karthikeyan, A.

A. Karthikeyan, S. Coulombe, and A. M. Kietzig, “Wetting behavior of multi-walled carbon nanotube nanofluids,” Nanotechnology 28(10), 105706 (2017).
[Crossref] [PubMed]

Kietzig, A. M.

A. Karthikeyan, S. Coulombe, and A. M. Kietzig, “Wetting behavior of multi-walled carbon nanotube nanofluids,” Nanotechnology 28(10), 105706 (2017).
[Crossref] [PubMed]

Lara-Romero, J.

J. A. Carlos-Cornelio, P. Andre-Cuervo, L. M. Hoyos-Palacios, J. Lara-Romero, and A. Toro, “Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system,” J. Mater. Res. Technol. 5(1), 68–76 (2016).
[Crossref]

Liu, C.

C. Liu, Y. Tanaka, and Y. Fujimoto, “Viscosity transient phenomenon during drop testing and its simple dynamics model,” World J. Mech. 5(03), 33–41 (2015).
[Crossref]

Lor, C.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Lubansky, A. S.

Márquez-Cruz, V. A.

Martello, D.

R. H. Chen, T. X. Phuoc, and D. Martello, “Surface tension of evaporating nano〉uid droplets,” Int. J. Heat Mass Transfer 54(11–12), 2459–2466 (2011).
[Crossref]

Martínez-González, C. L.

J. A. García-Merino, C. L. Martínez-González, C. R. Torres-San Miguel, M. Trejo-Valdez, H. Martínez-Gutiérrez, and C. Torres-Torres, “Photothermal, photoconductive and nonlinear optical effects induced by nanosecond pulse irradiation in multi-wall carbon nanotubes,” Mater. Sci. Eng. B 194, 27–33 (2015).
[Crossref]

Martínez-Gutiérrez, H.

J. A. García-Merino, C. L. Martínez-González, C. R. Torres-San Miguel, M. Trejo-Valdez, H. Martínez-Gutiérrez, and C. Torres-Torres, “Photothermal, photoconductive and nonlinear optical effects induced by nanosecond pulse irradiation in multi-wall carbon nanotubes,” Mater. Sci. Eng. B 194, 27–33 (2015).
[Crossref]

C. Torres-Torres, N. Peréa-López, H. Martínez-Gutiérrez, M. Trejo-Valdez, J. Ortíz-López, and M. Terrones, “Optoelectronic modulation by multi-wall carbon nanotubes,” Nanotechnology 24(4), 045201 (2013).
[Crossref] [PubMed]

E. Feria-Reyes, C. Torres-Torres, H. Martínez-Gutiérrez, S. Morales-Bonilla, R. Torres-Martínez, M. Trejo-Valdez, and G. Urriolagoitia-Calderón, “Mechano-optical modulation and optical limiting by multiwall carbon nanotubes,” J. Mod. Opt. 60(16), 1321–1326 (2013).
[Crossref]

Maultzsch, J.

J. Maultzsch, S. Reich, and C. Thomsen, “Chirality-selective Raman scattering of the D mode in carbon nanotubes,” Phys. Rev. B Condens. Matter 64(12), 121407 (2001).
[Crossref]

Merriam, E.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Morales-Bonilla, S.

E. Feria-Reyes, C. Torres-Torres, H. Martínez-Gutiérrez, S. Morales-Bonilla, R. Torres-Martínez, M. Trejo-Valdez, and G. Urriolagoitia-Calderón, “Mechano-optical modulation and optical limiting by multiwall carbon nanotubes,” J. Mod. Opt. 60(16), 1321–1326 (2013).
[Crossref]

Muller, J. M.

Mullins, R. D.

D. A. Fletcher and R. D. Mullins, “Cell mechanics and the cytoskeleton,” Nature 463(7280), 485–492 (2010).
[Crossref] [PubMed]

Murdoch, S.

S. Barland, S. Coen, M. Erkintalo, M. Giudici, J. Javaloyes, and S. Murdoch, “Temporal localized structured in optical resonators,” Adv. Phys. 2(3), 496–517 (2017).

Nesic, L.

D. Nikolić and L. Nesic, “Determination of surface tension coefficient of liquids by diffraction of light on capillary waves,” Eur. J. Phys. 33(6), 1677–1685 (2012).
[Crossref]

Nikolic, D.

D. Nikolić and L. Nesic, “Determination of surface tension coefficient of liquids by diffraction of light on capillary waves,” Eur. J. Phys. 33(6), 1677–1685 (2012).
[Crossref]

O’Hare, K. D.

K. D. O’Hare, P. L. Spedding, and J. Grimshaw, “Evaporation of the ethanol and water components comprising a binary liquid mixture,” Asia-Pac. J. Chem. Eng. 1(2–3), 118–128 (1993).

Ortíz-López, J.

C. Torres-Torres, N. Peréa-López, H. Martínez-Gutiérrez, M. Trejo-Valdez, J. Ortíz-López, and M. Terrones, “Optoelectronic modulation by multi-wall carbon nanotubes,” Nanotechnology 24(4), 045201 (2013).
[Crossref] [PubMed]

Pearce, R.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Peréa-López, N.

C. Torres-Torres, N. Peréa-López, H. Martínez-Gutiérrez, M. Trejo-Valdez, J. Ortíz-López, and M. Terrones, “Optoelectronic modulation by multi-wall carbon nanotubes,” Nanotechnology 24(4), 045201 (2013).
[Crossref] [PubMed]

Phuoc, T. X.

R. H. Chen, T. X. Phuoc, and D. Martello, “Surface tension of evaporating nano〉uid droplets,” Int. J. Heat Mass Transfer 54(11–12), 2459–2466 (2011).
[Crossref]

Rajasekharan-Unnithan, R.

Reich, S.

J. Maultzsch, S. Reich, and C. Thomsen, “Chirality-selective Raman scattering of the D mode in carbon nanotubes,” Phys. Rev. B Condens. Matter 64(12), 121407 (2001).
[Crossref]

Resto, P. J.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Schwartz, T.

Spedding, P. L.

K. D. O’Hare, P. L. Spedding, and J. Grimshaw, “Evaporation of the ethanol and water components comprising a binary liquid mixture,” Asia-Pac. J. Chem. Eng. 1(2–3), 118–128 (1993).

Stava, E.

P. J. Resto, A. Bhat, E. Stava, C. Lor, E. Merriam, R. E. Diaz-Rivera, R. Pearce, R. Blick, and J. C. Williams, “Flow characterization and patch clamp dose responses using jet microfluidics in a tubeless microfluidic device,” J. Neurosci. Methods 291, 182–189 (2017).
[Crossref] [PubMed]

Takaiwa, D.

D. Winarto, D. Takaiwa, E. Yamamoto, and K. Yasuoka, “Separation of water-ethanol solutions with carbon nanotubes and electric fields,” Phys. Chem. Chem. Phys. 18(48), 33310–33319 (2016).
[Crossref] [PubMed]

Tanaka, Y.

C. Liu, Y. Tanaka, and Y. Fujimoto, “Viscosity transient phenomenon during drop testing and its simple dynamics model,” World J. Mech. 5(03), 33–41 (2015).
[Crossref]

Tapp, D.

Taylor, J. M.

Terrones, M.

C. Torres-Torres, N. Peréa-López, H. Martínez-Gutiérrez, M. Trejo-Valdez, J. Ortíz-López, and M. Terrones, “Optoelectronic modulation by multi-wall carbon nanotubes,” Nanotechnology 24(4), 045201 (2013).
[Crossref] [PubMed]

Thomsen, C.

J. Maultzsch, S. Reich, and C. Thomsen, “Chirality-selective Raman scattering of the D mode in carbon nanotubes,” Phys. Rev. B Condens. Matter 64(12), 121407 (2001).
[Crossref]

Toro, A.

J. A. Carlos-Cornelio, P. Andre-Cuervo, L. M. Hoyos-Palacios, J. Lara-Romero, and A. Toro, “Tribological properties of carbon nanotubes as lubricant additive in oil and water for a wheel–rail system,” J. Mater. Res. Technol. 5(1), 68–76 (2016).
[Crossref]

Torres-Martínez, R.

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Figures (4)

Fig. 1
Fig. 1 (a) Three mirrors setup of the suspended drop in the optical fiber, (b) Nonlinear mechano-optical scheme sensing by a Fabry-Perot interferometer.
Fig. 2
Fig. 2 (a) TEM micrograph of a CNTs bundle, an inset shows the multiwall nature of an isolated tube. (b) Reflectance and (c) Transmittance spectral of the samples. (d) Transmission spectra difference between EtOH and EtOH-MWCNTs. (e) Calibration measurements of the samples in study. (f) Dynamical evaporation behavior of EtOH and EtOH-MWCNTs.
Fig. 3
Fig. 3 Image related to the interferometric patterns perturbed by a nanosecond 532 nm pulse (a) calibration without fluid, (b) distilled water, (c) EtOH, (d) MWCNTs nanofluid.
Fig. 4
Fig. 4 Dynamical mechano-optical behaviors in the studied samples (a) H2O, (b) EtOH, (c) EtOH-MWCNTs.

Tables (1)

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Table 1 Viscosity and surface tension of the studied samples.

Equations (4)

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R 3 = r 2 2 + r 3 2 + r 1 2 ( 1+ r 2 2 r 3 2 )+ D 3 1+ r 2 2 r 3 2 + r 1 2 ( r 2 2 + r 3 2 )+ D 3
D 3 =2 r 2 ( r 1 ( 1+ r 3 2 )cos[ 2 φ 1 ]+ r 1 r 2 r 3 cos[ 2 φ 1 2 φ 2 ] + r 3 ( 1+ r 1 2 )cos[ 2 φ 2 ] )+2 r 1 r 3 cos[ 2 φ 1 +2 φ 2 ]
m x ¨ (t)+ η x ˙ (t)+ γ x n (t)=fδ(0)
η α = η β η β η α ; γ α = γ β γ β γ α

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