Raman band intensities of tellurite glasses

V. G. Plotnichenko; V. O. Sokolov; V. V. Koltashev; E. M. Dianov; I. A. Grishin; M. F. Churbanov

doi:10.1364/OL.30.001156

Raman band intensities of tellurite glasses

V. G. Plotnichenko, V. O. Sokolov, V. V. Koltashev, E. M. Dianov, I. A. Grishin, and M. F. Churbanov

Optics Letters
Vol. 30,
Issue 10,
pp. 1156-1158
(2005)
•https://doi.org/10.1364/OL.30.001156

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V. G. Plotnichenko, V. O. Sokolov, V. V. Koltashev, E. M. Dianov, I. A. Grishin, and M. F. Churbanov, "Raman band intensities of tellurite glasses," Opt. Lett. 30, 1156-1158 (2005)

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Previously assigned OCIS codes
- Fiber materials (060.2290)
- Glass and other amorphous materials (160.2750)
- Spectroscopy, Raman (300.6450)

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- Original Manuscript: September 27, 2004
- Published: May 15, 2005

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Abstract

Raman spectra of ${TeO}_{2}$ -based glasses doped with ${WO}_{3}$ , ZnO, ${GeO}_{2}, {TiO}_{2}, {MoO}_{3}$ , and ${Sb}_{2} O_{3}$ are measured. The intensity of bands in the Raman spectra of ${MoO}_{3} - {TeO}_{2}$ and ${MoO}_{3} - {WO}_{3} - {TeO}_{2}$ glasses is shown to be 80–95 times higher than that for silica glass. It is shown that these glasses can be considered as one of the most promising materials for Raman fiber amplifiers.

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			Ratio of Intensities of the Raman Band and the $440 - {cm}^{- 1}$ band in ${SiO}_{2}$
Charge Composition, (mol. %)	Analysis Results (JEOL)	Factor F	$460 {cm}^{- 1}$	$650 - 750 {cm}^{- 1}$	$900 - 920 {cm}^{- 1}$
$10 {WO}_{3} - 90 {TeO}_{2}$	$12.5 {WO}_{3} - 87.5 {TeO}_{2}$	2.82	50	90 (668)	45
$15 {WO}_{3} - 85 {TeO}_{2}$	$14.8 {WO}_{3} - 85.2 {TeO}_{2}$	2.79	47	90 (668)	52
$20 {WO}_{3} - 80 {TeO}_{2}$	$18.9 {WO}_{3} - 81.1 {TeO}_{2}$	2.73	45	85 (672)	58
$25 {WO}_{3} - 75 {TeO}_{2}$	$24.8 {WO}_{3} - 75.2 {TeO}_{2}$	2.67	40	79 (685)	65
$20 ZnO - 80 {TeO}_{2}$	$21.4 ZnO - 79.6 {TeO}_{2}$	2.45	37	54 (736)	-
$25 ZnO - 75 {TeO}_{2}$	$22.9 ZnO - 77.1 {TeO}_{2}$	2.44	36	58 (738)	-
$30 ZnO - 70 {TeO}_{2}$	$28.8 ZnO - 71.2 {TeO}_{2}$	2.37	32	62 (748)	-
$35 ZnO - 65 {TeO}_{2}$	$33.3 ZnO - 66.7 {TeO}_{2}$	2.27	26.5	59 (752)	-
$15 {TiO}_{2} - 85 {TeO}_{2}$	$13.5 {TiO}_{2} - 86.5 {TeO}_{2}$	2.41	45	60 (660)	-
$10 {GeO}_{2} - 90 {TeO}_{2}$	$10.9 {GeO}_{2} - 89.1 {TeO}_{2}$	2.45	50	80 (665)	-
$17 {MoO}_{3} - 18 {WO}_{3} - 65 {TeO}_{2}$	$16.7 {MoO}_{3} - 19.6 {WO}_{3} - 63.7 {TeO}_{2}$	2.64	38	75 (720)	96
$14 {Sb}_{2} O_{3} - 86 {TeO}_{2}$	$2.1 {WO}_{3} - 19.1 {Sb}_{2} O_{3} - 78.8 {TeO}_{2}$	2.30	44	46 (665)	20
$30 {MoO}_{3} - 70 {TeO}_{2}$	$29.0 {MoO}_{3} - 71.0 {TeO}_{2}$	2.95	35	63 (740)	95

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