Abstract

Transparent conductive p-type Bi2Sr2Co2Oy thin films were epitaxial grown on LaAlO3 substrate by pulsed laser deposition. Film with thickness of 50 nm showed a room temperature resistivity of about 5.5 mΩ cm and an average optical transmittance of about 51% in the visible region, resulting in a significant high figure of merit of 1350 MΩ−1. This is one of the highest values reported for the p-type transparent conducting oxides, demonstrating that epitaxial Bi2Sr2Co2Oy thin films have great potential applications in optoelectronic devices.

© 2014 Optical Society of America

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  1. E. Arca, K. Fleischer, and I. V. Shvets, “Magnesium, nitrogen codoped Cr2O3: A p-type transparent conducting oxide,” Appl. Phys. Lett. 99(11), 111910 (2011).
    [Crossref]
  2. K. Ellmer, “Past achievements and future challenges in the development of optically transparent electrodes,” Nat. Photonics 6(12), 809–817 (2012).
    [Crossref]
  3. K. Fleischer, E. Arca, and I. V. Shvets, “Improving solar cell efficiency with optically optimized TCO layers,” Sol. Energy Mater. Sol. Cells 101, 262–269 (2012).
    [Crossref]
  4. A. Dhar and T. L. Alford, “High quality transparent TiO2/Ag/TiO2 composite electrode films deposited on flexible substrate at room temperature by sputtering,” APL Mater. 1(1), 012102 (2013).
    [Crossref]
  5. G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
    [Crossref] [PubMed]
  6. H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
    [Crossref]
  7. H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
    [Crossref]
  8. M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
    [Crossref]
  9. P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
    [Crossref] [PubMed]
  10. H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
    [Crossref]
  11. M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
    [Crossref] [PubMed]
  12. N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
    [Crossref] [PubMed]
  13. K. Koumoto, I. Terasaki, and R. Funahashi, “Complex oxide materials for potential thermoelectric applications,” MRS Bull. 31(03), 206–210 (2006).
    [Crossref]
  14. R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
    [Crossref] [PubMed]
  15. M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
    [Crossref]
  16. T. Yamamoto, K. Uchinokura, and I. Tsukada, “Physical properties of the misfit-layered (Bi,Pb)-Sr-Co-O system: Effect of hole doping into a triangular lattice formed by low-spin Co ions,” Phys. Rev. B 65(18), 184434 (2002).
    [Crossref]

2014 (3)

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
[Crossref]

2013 (2)

A. Dhar and T. L. Alford, “High quality transparent TiO2/Ag/TiO2 composite electrode films deposited on flexible substrate at room temperature by sputtering,” APL Mater. 1(1), 012102 (2013).
[Crossref]

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

2012 (3)

K. Ellmer, “Past achievements and future challenges in the development of optically transparent electrodes,” Nat. Photonics 6(12), 809–817 (2012).
[Crossref]

K. Fleischer, E. Arca, and I. V. Shvets, “Improving solar cell efficiency with optically optimized TCO layers,” Sol. Energy Mater. Sol. Cells 101, 262–269 (2012).
[Crossref]

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

2011 (3)

N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
[Crossref] [PubMed]

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

E. Arca, K. Fleischer, and I. V. Shvets, “Magnesium, nitrogen codoped Cr2O3: A p-type transparent conducting oxide,” Appl. Phys. Lett. 99(11), 111910 (2011).
[Crossref]

2007 (1)

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

2006 (2)

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

K. Koumoto, I. Terasaki, and R. Funahashi, “Complex oxide materials for potential thermoelectric applications,” MRS Bull. 31(03), 206–210 (2006).
[Crossref]

2002 (1)

T. Yamamoto, K. Uchinokura, and I. Tsukada, “Physical properties of the misfit-layered (Bi,Pb)-Sr-Co-O system: Effect of hole doping into a triangular lattice formed by low-spin Co ions,” Phys. Rev. B 65(18), 184434 (2002).
[Crossref]

1997 (1)

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Aksit, M.

M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
[Crossref]

Alford, T. L.

A. Dhar and T. L. Alford, “High quality transparent TiO2/Ag/TiO2 composite electrode films deposited on flexible substrate at room temperature by sputtering,” APL Mater. 1(1), 012102 (2013).
[Crossref]

Arca, E.

K. Fleischer, E. Arca, and I. V. Shvets, “Improving solar cell efficiency with optically optimized TCO layers,” Sol. Energy Mater. Sol. Cells 101, 262–269 (2012).
[Crossref]

E. Arca, K. Fleischer, and I. V. Shvets, “Magnesium, nitrogen codoped Cr2O3: A p-type transparent conducting oxide,” Appl. Phys. Lett. 99(11), 111910 (2011).
[Crossref]

Bauer, E.

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

Burrell, A. K.

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

Cava, R. J.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Ceder, G.

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

Chen, C.-H.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Chen, H.-Y.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Chu, J. H.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Dai, J. M.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Dai, X.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Dhar, A.

A. Dhar and T. L. Alford, “High quality transparent TiO2/Ag/TiO2 composite electrode films deposited on flexible substrate at room temperature by sputtering,” APL Mater. 1(1), 012102 (2013).
[Crossref]

Dong, C.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Ellmer, K.

K. Ellmer, “Past achievements and future challenges in the development of optically transparent electrodes,” Nat. Photonics 6(12), 809–817 (2012).
[Crossref]

Fleischer, K.

K. Fleischer, E. Arca, and I. V. Shvets, “Improving solar cell efficiency with optically optimized TCO layers,” Sol. Energy Mater. Sol. Cells 101, 262–269 (2012).
[Crossref]

E. Arca, K. Fleischer, and I. V. Shvets, “Magnesium, nitrogen codoped Cr2O3: A p-type transparent conducting oxide,” Appl. Phys. Lett. 99(11), 111910 (2011).
[Crossref]

Foo, M. L.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Funahashi, R.

K. Koumoto, I. Terasaki, and R. Funahashi, “Complex oxide materials for potential thermoelectric applications,” MRS Bull. 31(03), 206–210 (2006).
[Crossref]

Gonze, X.

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

Han, M. J.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Hautier, G.

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

Hosono, H.

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Hu, L.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Hu, Z. G.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Hui, Z. Z.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Hyodo, H.

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Jain, M. K.

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

Jia, Q. X.

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

Jian, J.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Jiang, K.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Kawazoe, H.

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Kolli, S. K.

M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
[Crossref]

Koumoto, K.

K. Koumoto, I. Terasaki, and R. Funahashi, “Complex oxide materials for potential thermoelectric applications,” MRS Bull. 31(03), 206–210 (2006).
[Crossref]

Kurita, M.

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Lee, M.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Li, L.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Li, Y. W.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Linderoth, S.

N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
[Crossref] [PubMed]

Liu, K.-L.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Lou, Y. H.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Lu, X.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Luo, H. M.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

Luo, X.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

McCleskey, T. M.

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

Miglio, A.

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

Ohtaki, M.

N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
[Crossref] [PubMed]

Ong, N. P.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Pascal, R. A.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Pryds, N.

N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
[Crossref] [PubMed]

Rignanese, G.-M.

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

Robinson, R. D.

M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
[Crossref]

Shvets, I. V.

K. Fleischer, E. Arca, and I. V. Shvets, “Improving solar cell efficiency with optically optimized TCO layers,” Sol. Energy Mater. Sol. Cells 101, 262–269 (2012).
[Crossref]

E. Arca, K. Fleischer, and I. V. Shvets, “Magnesium, nitrogen codoped Cr2O3: A p-type transparent conducting oxide,” Appl. Phys. Lett. 99(11), 111910 (2011).
[Crossref]

Slauch, I. M.

M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
[Crossref]

Song, P. Y.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Song, W. H.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Su, H.-C.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Sun, Y. H.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Sun, Y. P.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Tang, X. W.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Terasaki, I.

K. Koumoto, I. Terasaki, and R. Funahashi, “Complex oxide materials for potential thermoelectric applications,” MRS Bull. 31(03), 206–210 (2006).
[Crossref]

Tsai, C.-M.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Tsukada, I.

T. Yamamoto, K. Uchinokura, and I. Tsukada, “Physical properties of the misfit-layered (Bi,Pb)-Sr-Co-O system: Effect of hole doping into a triangular lattice formed by low-spin Co ions,” Phys. Rev. B 65(18), 184434 (2002).
[Crossref]

Uchinokura, K.

T. Yamamoto, K. Uchinokura, and I. Tsukada, “Physical properties of the misfit-layered (Bi,Pb)-Sr-Co-O system: Effect of hole doping into a triangular lattice formed by low-spin Co ions,” Phys. Rev. B 65(18), 184434 (2002).
[Crossref]

Van Nong, N.

N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
[Crossref] [PubMed]

Viciu, L.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Wang, H. Y.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Wang, Y. Y.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Watauchi, S.

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Wei, R. H.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Yamamoto, T.

T. Yamamoto, K. Uchinokura, and I. Tsukada, “Physical properties of the misfit-layered (Bi,Pb)-Sr-Co-O system: Effect of hole doping into a triangular lattice formed by low-spin Co ions,” Phys. Rev. B 65(18), 184434 (2002).
[Crossref]

Yanagi, H.

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Yang, H.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Yang, J.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Yang, Z. R.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Yasukawa, M.

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Yen, S.-J.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Yew, T.-R.

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

Yi, Q. H.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Yu, W. L.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Zhai, P. F.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Zhang, J. Z.

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

Zhao, J.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Zhu, X. B.

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

Zou, G. F.

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

Adv. Mater. (2)

H. M. Luo, M. K. Jain, T. M. McCleskey, E. Bauer, A. K. Burrell, and Q. X. Jia, “Optical and structural properties of single phase epitaxial p-type transparent oxide thin films,” Adv. Mater. 19(21), 3604–3607 (2007).
[Crossref]

N. Van Nong, N. Pryds, S. Linderoth, and M. Ohtaki, “Enhancement of the thermoelectric performance of p-type layered oxide Ca₃Co₄O9+δ through heavy doping and metallic nanoinclusions,” Adv. Mater. 23(21), 2484–2490 (2011).
[Crossref] [PubMed]

APL Mater. (1)

A. Dhar and T. L. Alford, “High quality transparent TiO2/Ag/TiO2 composite electrode films deposited on flexible substrate at room temperature by sputtering,” APL Mater. 1(1), 012102 (2013).
[Crossref]

Appl. Phys. Lett. (2)

E. Arca, K. Fleischer, and I. V. Shvets, “Magnesium, nitrogen codoped Cr2O3: A p-type transparent conducting oxide,” Appl. Phys. Lett. 99(11), 111910 (2011).
[Crossref]

M. Aksit, S. K. Kolli, I. M. Slauch, and R. D. Robinson, “Misfit layered Ca3Co4O9 as a high figure of merit p-type transparent conducting oxide film through solution processing,” Appl. Phys. Lett. 104(16), 161901 (2014).
[Crossref]

Chem. Commun. (Camb.) (2)

R. H. Wei, X. W. Tang, L. Hu, Z. Z. Hui, J. Yang, H. M. Luo, X. Luo, J. M. Dai, W. H. Song, Z. R. Yang, X. B. Zhu, and Y. P. Sun, “Transparent conducting p-type thin films of c-axis self-oriented Bi₂Sr₂Co₂Oy with high figure of merit,” Chem. Commun. (Camb.) 50(68), 9697–9699 (2014).
[Crossref] [PubMed]

P. F. Zhai, Q. H. Yi, J. Jian, H. Y. Wang, P. Y. Song, C. Dong, X. Lu, Y. H. Sun, J. Zhao, X. Dai, Y. H. Lou, H. Yang, and G. F. Zou, “Transparent p-type epitaxial thin films of nickel oxide,” Chem. Commun. (Camb.) 50(15), 1854–1856 (2014).
[Crossref] [PubMed]

J. Mater. Chem. (2)

H.-Y. Chen, H.-C. Su, C.-H. Chen, K.-L. Liu, C.-M. Tsai, S.-J. Yen, and T.-R. Yew, “Indium-doped molybdenum oxide as a new p-type transparent conductive oxide,” J. Mater. Chem. 21(15), 5745–5752 (2011).
[Crossref]

M. J. Han, K. Jiang, J. Z. Zhang, W. L. Yu, Y. W. Li, Z. G. Hu, and J. H. Chu, “Structural, electronic band transition and optoelectronic properties of delafossite CuGa1-xCrxO2 (0 < x< 1) solid solution films grown by the sol–gel method,” J. Mater. Chem. 22(35), 18463–18470 (2012).
[Crossref]

MRS Bull. (1)

K. Koumoto, I. Terasaki, and R. Funahashi, “Complex oxide materials for potential thermoelectric applications,” MRS Bull. 31(03), 206–210 (2006).
[Crossref]

Nat Commun (1)

G. Hautier, A. Miglio, G. Ceder, G.-M. Rignanese, and X. Gonze, “Identification and design principles of low hole effective mass p-type transparent conducting oxides,” Nat Commun 4, 2292 (2013).
[Crossref] [PubMed]

Nat. Mater. (1)

M. Lee, L. Viciu, L. Li, Y. Y. Wang, M. L. Foo, S. Watauchi, R. A. Pascal, R. J. Cava, and N. P. Ong, “Large enhancement of the thermopower in NaxCoO2 at high Na doping,” Nat. Mater. 5(7), 537–540 (2006).
[Crossref] [PubMed]

Nat. Photonics (1)

K. Ellmer, “Past achievements and future challenges in the development of optically transparent electrodes,” Nat. Photonics 6(12), 809–817 (2012).
[Crossref]

Nature (1)

H. Kawazoe, M. Yasukawa, H. Hyodo, M. Kurita, H. Yanagi, and H. Hosono, “P-type electrical conduction in transparent thin films of CuAlO2,” Nature 389(6654), 939–942 (1997).
[Crossref]

Phys. Rev. B (1)

T. Yamamoto, K. Uchinokura, and I. Tsukada, “Physical properties of the misfit-layered (Bi,Pb)-Sr-Co-O system: Effect of hole doping into a triangular lattice formed by low-spin Co ions,” Phys. Rev. B 65(18), 184434 (2002).
[Crossref]

Sol. Energy Mater. Sol. Cells (1)

K. Fleischer, E. Arca, and I. V. Shvets, “Improving solar cell efficiency with optically optimized TCO layers,” Sol. Energy Mater. Sol. Cells 101, 262–269 (2012).
[Crossref]

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Figures (4)

Fig. 1
Fig. 1 XRD (a) θ-2θ scan of the PLD-processed BSCO film on LAO substrate and (b) φ scans of the BSCO film and LAO substrate.
Fig. 2
Fig. 2 (a) TEM and (b) high resolution TEM of BSCO/LAO interface. The inset of Fig. 2 (a) is the SEAD pattern taken from the film part.
Fig. 3
Fig. 3 (a) low and (b) high magnification surface SEM images of the PLD-processed BSCO film.
Fig. 4
Fig. 4 (a) Temperature dependence of resistivity of the PLD-processed BSCO thin film, the inset is the Seebeck coefficient of the film; (b) photograph of the BSCO thin film on a labeled paper; (c) transmittance spectra of the BSCO thin film after abstracting the substrate contribution. The inset shows the transmittance spectra of bare LAO substrate as well as BSCO thin film on the LAO substrate; (d) (αhν)2 versus hν plot of BSCO thin film.

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