Abstract

PETTA/PETTG optical resin, a kind of LED encapsulating resin with high refractive index, was prepared via click chemistry method in this study. Optical and thermal properties of this resin were investigated with UV–Vis scanning spectrophotometer, Abbe refractometer and thermogravimetric analyses (TGA), respectively. The results show that the light transmitance of this resin can arrive up to 93% and its refractive index is 1.556, which is higher than those of silicone resins. Meanwhile, the cured PETTA/PETTG resin demonstrates the equal thermal stability to silicone resins, and its 5% weight loss temperature was about 350 °C. Therefore, the cured PETTA/PETTG resin could be used as an alternate of expensive silicone resins in LED encapsulation.

© 2015 Optical Society of America

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References

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  1. M. Ma, F. W. Mont, X. Yan, J. Cho, E. F. Schubert, G. B. Kim, and C. Sone, “Effects of the refractive index of theencapsulant on the light-extraction efficiency of light-emitting diodes,” Opt. Express 19(5), A1135–A1140 (2011).
    [Crossref] [PubMed]
  2. S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
    [Crossref]
  3. H. C. Kolb, M. G. Finn, and K. B. Sharpless, “Click chemistry: diverse chemical function from a few good reactions,” Angew. Chem. Int. Ed. Engl. 40(11), 2004–2021 (2001).
    [Crossref] [PubMed]
  4. J. Liu and M. Ueda, “High refractive index polymers: fundamental research and practical applications,” J. Mater. Chem. 19(47), 8907–8919 (2009).
    [Crossref]
  5. S. D. Bhagat, J. Chatterjee, and A. E. Stiegman, “High refractive index polymers based on thiol-ene cross-linking using polarizable inorganic/organic monomers,” Macromolecules 45(3), 1174–1181 (2012).
    [Crossref]
  6. J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
    [Crossref]
  7. D. Burget, C. Mallein, and J. P. Fouassier, “Photopolymerization of thiol-allyl ether and thiol-acrylate coatings with visible light photosensitive systems,” Polymer (Guildf.) 45(19), 6561–6567 (2004).
    [Crossref]
  8. Q. Li, H. Zhou, and C. E. Hoyle, “The effect of thiol and ene structures on thiol-ene networks: photopolymerization, physical, mechanical and optical properties,” Polymer (Guildf.) 50(10), 2237–2245 (2009).
    [Crossref]
  9. J. Shin, S. Nazarenko, and C. E. Hoyle, “Enthalpy relaxation of photopolymerized thiol-ene networks: structural effects,” Macromolecules 41(18), 6741–6746 (2008).
    [Crossref]
  10. N. B. Cramer, J. P. Scott, and C. N. Bowman, “Photopolymerizations of thiol-ene polymers without photoinitiators,” Macromolecules 35(14), 5361–5365 (2002).
    [Crossref]
  11. B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
    [Crossref]
  12. R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
    [Crossref]
  13. Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
    [Crossref]
  14. Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
    [Crossref]
  15. Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
    [Crossref]
  16. H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
    [Crossref]
  17. J. S. Kim, S. C. Yang, and B. S. Bae, “Thermally stable transparent sol-gel based siloxane hybrid material with high refractive index for light emitting diode (LED) encapsulation,” Chem. Mater. 22(11), 3549–3555 (2010).
    [Crossref]
  18. N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
    [Crossref]

2013 (2)

B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
[Crossref]

N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
[Crossref]

2012 (2)

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
[Crossref]

S. D. Bhagat, J. Chatterjee, and A. E. Stiegman, “High refractive index polymers based on thiol-ene cross-linking using polarizable inorganic/organic monomers,” Macromolecules 45(3), 1174–1181 (2012).
[Crossref]

2011 (1)

2010 (4)

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
[Crossref]

H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
[Crossref]

J. S. Kim, S. C. Yang, and B. S. Bae, “Thermally stable transparent sol-gel based siloxane hybrid material with high refractive index for light emitting diode (LED) encapsulation,” Chem. Mater. 22(11), 3549–3555 (2010).
[Crossref]

2009 (4)

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
[Crossref]

J. Liu and M. Ueda, “High refractive index polymers: fundamental research and practical applications,” J. Mater. Chem. 19(47), 8907–8919 (2009).
[Crossref]

J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
[Crossref]

Q. Li, H. Zhou, and C. E. Hoyle, “The effect of thiol and ene structures on thiol-ene networks: photopolymerization, physical, mechanical and optical properties,” Polymer (Guildf.) 50(10), 2237–2245 (2009).
[Crossref]

2008 (2)

J. Shin, S. Nazarenko, and C. E. Hoyle, “Enthalpy relaxation of photopolymerized thiol-ene networks: structural effects,” Macromolecules 41(18), 6741–6746 (2008).
[Crossref]

R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
[Crossref]

2004 (1)

D. Burget, C. Mallein, and J. P. Fouassier, “Photopolymerization of thiol-allyl ether and thiol-acrylate coatings with visible light photosensitive systems,” Polymer (Guildf.) 45(19), 6561–6567 (2004).
[Crossref]

2002 (1)

N. B. Cramer, J. P. Scott, and C. N. Bowman, “Photopolymerizations of thiol-ene polymers without photoinitiators,” Macromolecules 35(14), 5361–5365 (2002).
[Crossref]

2001 (1)

H. C. Kolb, M. G. Finn, and K. B. Sharpless, “Click chemistry: diverse chemical function from a few good reactions,” Angew. Chem. Int. Ed. Engl. 40(11), 2004–2021 (2001).
[Crossref] [PubMed]

Ando, S.

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
[Crossref]

R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
[Crossref]

Bae, B. S.

J. S. Kim, S. C. Yang, and B. S. Bae, “Thermally stable transparent sol-gel based siloxane hybrid material with high refractive index for light emitting diode (LED) encapsulation,” Chem. Mater. 22(11), 3549–3555 (2010).
[Crossref]

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

Bhagat, S. D.

S. D. Bhagat, J. Chatterjee, and A. E. Stiegman, “High refractive index polymers based on thiol-ene cross-linking using polarizable inorganic/organic monomers,” Macromolecules 45(3), 1174–1181 (2012).
[Crossref]

Bowman, C. N.

H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
[Crossref]

N. B. Cramer, J. P. Scott, and C. N. Bowman, “Photopolymerizations of thiol-ene polymers without photoinitiators,” Macromolecules 35(14), 5361–5365 (2002).
[Crossref]

Burget, D.

D. Burget, C. Mallein, and J. P. Fouassier, “Photopolymerization of thiol-allyl ether and thiol-acrylate coatings with visible light photosensitive systems,” Polymer (Guildf.) 45(19), 6561–6567 (2004).
[Crossref]

Chan, J. W.

J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
[Crossref]

Chatterjee, J.

S. D. Bhagat, J. Chatterjee, and A. E. Stiegman, “High refractive index polymers based on thiol-ene cross-linking using polarizable inorganic/organic monomers,” Macromolecules 45(3), 1174–1181 (2012).
[Crossref]

Cho, J.

Cramer, N. B.

N. B. Cramer, J. P. Scott, and C. N. Bowman, “Photopolymerizations of thiol-ene polymers without photoinitiators,” Macromolecules 35(14), 5361–5365 (2002).
[Crossref]

Finn, M. G.

H. C. Kolb, M. G. Finn, and K. B. Sharpless, “Click chemistry: diverse chemical function from a few good reactions,” Angew. Chem. Int. Ed. Engl. 40(11), 2004–2021 (2001).
[Crossref] [PubMed]

Fouassier, J. P.

D. Burget, C. Mallein, and J. P. Fouassier, “Photopolymerization of thiol-allyl ether and thiol-acrylate coatings with visible light photosensitive systems,” Polymer (Guildf.) 45(19), 6561–6567 (2004).
[Crossref]

Gao, N.

N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
[Crossref]

Higashihara, T.

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
[Crossref]

Hoyle, C. E.

H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
[Crossref]

Q. Li, H. Zhou, and C. E. Hoyle, “The effect of thiol and ene structures on thiol-ene networks: photopolymerization, physical, mechanical and optical properties,” Polymer (Guildf.) 50(10), 2237–2245 (2009).
[Crossref]

J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
[Crossref]

J. Shin, S. Nazarenko, and C. E. Hoyle, “Enthalpy relaxation of photopolymerized thiol-ene networks: structural effects,” Macromolecules 41(18), 6741–6746 (2008).
[Crossref]

Jin, J. H.

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

Kim, G. B.

Kim, J. S.

J. S. Kim, S. C. Yang, and B. S. Bae, “Thermally stable transparent sol-gel based siloxane hybrid material with high refractive index for light emitting diode (LED) encapsulation,” Chem. Mater. 22(11), 3549–3555 (2010).
[Crossref]

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

Kolb, H. C.

H. C. Kolb, M. G. Finn, and K. B. Sharpless, “Click chemistry: diverse chemical function from a few good reactions,” Angew. Chem. Int. Ed. Engl. 40(11), 2004–2021 (2001).
[Crossref] [PubMed]

Kwak, S. Y.

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

Li, Q.

Q. Li, H. Zhou, and C. E. Hoyle, “The effect of thiol and ene structures on thiol-ene networks: photopolymerization, physical, mechanical and optical properties,” Polymer (Guildf.) 50(10), 2237–2245 (2009).
[Crossref]

Liu, J.

J. Liu and M. Ueda, “High refractive index polymers: fundamental research and practical applications,” J. Mater. Chem. 19(47), 8907–8919 (2009).
[Crossref]

Liu, W. Q.

N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
[Crossref]

Lowe, A. B.

J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
[Crossref]

Ma, M.

Mallein, C.

D. Burget, C. Mallein, and J. P. Fouassier, “Photopolymerization of thiol-allyl ether and thiol-acrylate coatings with visible light photosensitive systems,” Polymer (Guildf.) 45(19), 6561–6567 (2004).
[Crossref]

Matsushima, H.

H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
[Crossref]

Mont, F. W.

Nazarenko, S.

J. Shin, S. Nazarenko, and C. E. Hoyle, “Enthalpy relaxation of photopolymerized thiol-ene networks: structural effects,” Macromolecules 41(18), 6741–6746 (2008).
[Crossref]

Okutsu, R.

R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
[Crossref]

Qin, A. J.

B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
[Crossref]

Schubert, E. F.

Scott, J. P.

N. B. Cramer, J. P. Scott, and C. N. Bowman, “Photopolymerizations of thiol-ene polymers without photoinitiators,” Macromolecules 35(14), 5361–5365 (2002).
[Crossref]

Sharpless, K. B.

H. C. Kolb, M. G. Finn, and K. B. Sharpless, “Click chemistry: diverse chemical function from a few good reactions,” Angew. Chem. Int. Ed. Engl. 40(11), 2004–2021 (2001).
[Crossref] [PubMed]

Shin, J.

H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
[Crossref]

J. Shin, S. Nazarenko, and C. E. Hoyle, “Enthalpy relaxation of photopolymerized thiol-ene networks: structural effects,” Macromolecules 41(18), 6741–6746 (2008).
[Crossref]

Sone, C.

Stiegman, A. E.

S. D. Bhagat, J. Chatterjee, and A. E. Stiegman, “High refractive index polymers based on thiol-ene cross-linking using polarizable inorganic/organic monomers,” Macromolecules 45(3), 1174–1181 (2012).
[Crossref]

Sun, J. Z.

B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
[Crossref]

Suzuki, Y.

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
[Crossref]

R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
[Crossref]

Tang, B. Z.

B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
[Crossref]

Ueda, M.

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
[Crossref]

J. Liu and M. Ueda, “High refractive index polymers: fundamental research and practical applications,” J. Mater. Chem. 19(47), 8907–8919 (2009).
[Crossref]

R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
[Crossref]

Wang, Z. F.

N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
[Crossref]

Yan, X.

Yan, Z. L.

N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
[Crossref]

Yang, S. C.

J. S. Kim, S. C. Yang, and B. S. Bae, “Thermally stable transparent sol-gel based siloxane hybrid material with high refractive index for light emitting diode (LED) encapsulation,” Chem. Mater. 22(11), 3549–3555 (2010).
[Crossref]

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

Yao, B. C.

B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
[Crossref]

Zhou, H.

Q. Li, H. Zhou, and C. E. Hoyle, “The effect of thiol and ene structures on thiol-ene networks: photopolymerization, physical, mechanical and optical properties,” Polymer (Guildf.) 50(10), 2237–2245 (2009).
[Crossref]

J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
[Crossref]

Angew. Chem. Int. Ed. Engl. (1)

H. C. Kolb, M. G. Finn, and K. B. Sharpless, “Click chemistry: diverse chemical function from a few good reactions,” Angew. Chem. Int. Ed. Engl. 40(11), 2004–2021 (2001).
[Crossref] [PubMed]

Chem. Mater. (2)

J. W. Chan, H. Zhou, C. E. Hoyle, and A. B. Lowe, “Photopolymerization of thiol-alkynes: polysulfide networks,” Chem. Mater. 21(8), 1579–1585 (2009).
[Crossref]

J. S. Kim, S. C. Yang, and B. S. Bae, “Thermally stable transparent sol-gel based siloxane hybrid material with high refractive index for light emitting diode (LED) encapsulation,” Chem. Mater. 22(11), 3549–3555 (2010).
[Crossref]

Chin. Sci. Bull. (1)

B. C. Yao, J. Z. Sun, A. J. Qin, and B. Z. Tang, “Thiol-yne click polymerization,” Chin. Sci. Bull. 58(22), 2711–2718 (2013).
[Crossref]

Eur. Polym. J. (1)

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers,” Eur. Polym. J. 46(1), 34–41 (2010).
[Crossref]

J. Appl. Polym. Sci. (1)

S. C. Yang, J. S. Kim, J. H. Jin, S. Y. Kwak, and B. S. Bae, “Thermal resistance of cycloaliphatic epoxy hybrimer based on sol-gelderived oligosiloxane for LED encapsulation,” J. Appl. Polym. Sci. 117(4), 2140–2145 (2010).
[Crossref]

J. Mater. Chem. (1)

J. Liu and M. Ueda, “High refractive index polymers: fundamental research and practical applications,” J. Mater. Chem. 19(47), 8907–8919 (2009).
[Crossref]

J. Polym. Sci. A Polym. Chem. (1)

H. Matsushima, J. Shin, C. N. Bowman, and C. E. Hoyle, “Thiol-isocyanate-acrylate ternary networks by selective thiol-click chemistry,” J. Polym. Sci. A Polym. Chem. 48(15), 3255–3264 (2010).
[Crossref]

Macromolecules (5)

R. Okutsu, Y. Suzuki, S. Ando, and M. Ueda, “Poly(thioether sulfone) with high refractive index and high Abbe’s number,” Macromolecules 41(16), 6165–6168 (2008).
[Crossref]

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis and characterization of high refractive index and high Abbe’s number poly (thioether sulfone)s based on tricyclo decane moiety,” Macromolecules 45(8), 3402–3408 (2012).
[Crossref]

S. D. Bhagat, J. Chatterjee, and A. E. Stiegman, “High refractive index polymers based on thiol-ene cross-linking using polarizable inorganic/organic monomers,” Macromolecules 45(3), 1174–1181 (2012).
[Crossref]

J. Shin, S. Nazarenko, and C. E. Hoyle, “Enthalpy relaxation of photopolymerized thiol-ene networks: structural effects,” Macromolecules 41(18), 6741–6746 (2008).
[Crossref]

N. B. Cramer, J. P. Scott, and C. N. Bowman, “Photopolymerizations of thiol-ene polymers without photoinitiators,” Macromolecules 35(14), 5361–5365 (2002).
[Crossref]

Opt. Express (1)

Opt. Mater. (1)

N. Gao, W. Q. Liu, Z. L. Yan, and Z. F. Wang, “Synthesis and properties of transparent cycloaliphatic epoxy–silicone resins for opto-electronic devices packaging,” Opt. Mater. 35(3), 567–575 (2013).
[Crossref]

Polym. J. (1)

Y. Suzuki, T. Higashihara, S. Ando, and M. Ueda, “Synthesis of high refractive index poly (thioether sulfone)s with high Abbe’s number derived from 2,5-bis(sulfanylmethyl)-1,4-dithiane,” Polym. J. 41(10), 860–865 (2009).
[Crossref]

Polymer (Guildf.) (2)

D. Burget, C. Mallein, and J. P. Fouassier, “Photopolymerization of thiol-allyl ether and thiol-acrylate coatings with visible light photosensitive systems,” Polymer (Guildf.) 45(19), 6561–6567 (2004).
[Crossref]

Q. Li, H. Zhou, and C. E. Hoyle, “The effect of thiol and ene structures on thiol-ene networks: photopolymerization, physical, mechanical and optical properties,” Polymer (Guildf.) 50(10), 2237–2245 (2009).
[Crossref]

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Figures (5)

Fig. 1
Fig. 1 The molecular structure of the samples and the reaction equation.
Fig. 2
Fig. 2 FTIR spectra of PETTA, PETTG, and the mixture of PETTA/PETTG before and after solidification.
Fig. 3
Fig. 3 The light transmittance of the PETTA/PETTG cured resin.
Fig. 4
Fig. 4 DSC curves of PETTA/PETTG mixtures in the scanning of two times.
Fig. 5
Fig. 5 TGA curves of PETTA/PETTG cured resin.

Tables (1)

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Table 1 DSC results of PETTA/PETTG and PETTA/OBDMT

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