Abstract

Eu3+ luminescence is helpful to probe the local structure of luminescent centers in a host lattice. In order to analyze the site occupancy and luminescence properties of Eu3+ in double salt silicate Na3LuSi3O9, Na3LuSi3O9:Eu3+ phosphors were prepared using a high temperature solid-state reaction method, and their luminescence spectra and decay curves under UV excitation were determined. According to the characteristic emission of O2- - Eu3+ charge transfer bands, 5D0-7F0, 5D0-7F1 and 5D0-7F2 transitions of Eu3+ in Na3LuSi3O9, the site occupancy of Eu3+ in the host Na3LuSi3O9 was clarified, which will be of benefit to the development of new luminescence materials based on the double salts silicates host Na3LuSi3O9.

© 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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  1. J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
    [Crossref]
  2. H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
    [Crossref]
  3. P. Dorenbos, “The Eu3+ charge transfer energy and the relation with the band gap of compounds,” J. Lumin. 111(1–2), 89–104 (2005).
    [Crossref]
  4. Z. J. Wang, P. Wang, J. P. Zhong, H. B. Liang, and J. Wang, “Luminescence properties of lutetium based red emitting phosphor NaLu(WO4)2:Eu3+,” Opt. Mater. Express 3(3), 418–425 (2013).
    [Crossref]
  5. F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
    [Crossref]
  6. G. Blasse, “The ultraviolet absorption bands of Bi3+ and Eu3+ in oxides,” J. Solid State Chem. 4(1), 52–54 (1972).
    [Crossref]
  7. F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
    [Crossref] [PubMed]
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    [Crossref]
  9. P. Dorenbos, “Systematic behaviour in trivalent lanthanide charge transfer energies,” J. Phys. Condens. Matter 15(49), 8417–8434 (2003).
    [Crossref]
  10. J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
    [Crossref]
  11. Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
    [Crossref]
  12. H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
    [Crossref]
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    [Crossref]
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    [Crossref]
  16. Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
    [Crossref]

2017 (1)

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

2016 (1)

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

2015 (1)

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

2013 (2)

Z. J. Wang, P. Wang, J. P. Zhong, H. B. Liang, and J. Wang, “Luminescence properties of lutetium based red emitting phosphor NaLu(WO4)2:Eu3+,” Opt. Mater. Express 3(3), 418–425 (2013).
[Crossref]

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

2011 (3)

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
[Crossref] [PubMed]

2009 (1)

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
[Crossref]

2008 (1)

Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
[Crossref]

2005 (1)

P. Dorenbos, “The Eu3+ charge transfer energy and the relation with the band gap of compounds,” J. Lumin. 111(1–2), 89–104 (2005).
[Crossref]

2003 (1)

P. Dorenbos, “Systematic behaviour in trivalent lanthanide charge transfer energies,” J. Phys. Condens. Matter 15(49), 8417–8434 (2003).
[Crossref]

1995 (1)

J. C. Krupa, “Optical excitations in lanthanide and actinide compounds,” J. Alloys Compd. 225(1–2), 1–10 (1995).
[Crossref]

1972 (1)

G. Blasse, “The ultraviolet absorption bands of Bi3+ and Eu3+ in oxides,” J. Solid State Chem. 4(1), 52–54 (1972).
[Crossref]

1971 (1)

1962 (1)

C. K. Jørgensen, “Electron transfer spectra of lanthanide complexes,” Mol. Phys. 5(3), 271–277 (1962).
[Crossref]

Bentley, F. F.

Bian, H. Y.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

Blasse, G.

G. Blasse, “The ultraviolet absorption bands of Bi3+ and Eu3+ in oxides,” J. Solid State Chem. 4(1), 52–54 (1972).
[Crossref]

Chen, J. Y.

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

Deng, D. G.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Dorenbos, P.

P. Dorenbos, “The Eu3+ charge transfer energy and the relation with the band gap of compounds,” J. Lumin. 111(1–2), 89–104 (2005).
[Crossref]

P. Dorenbos, “Systematic behaviour in trivalent lanthanide charge transfer energies,” J. Phys. Condens. Matter 15(49), 8417–8434 (2003).
[Crossref]

Du, F.

F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
[Crossref] [PubMed]

Du, F. P.

F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Dujardin, C.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

Fateley, W.

Gong, M. H.

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
[Crossref]

Guo, C. F.

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

Hao, Y.

Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
[Crossref]

Hua, Y.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Huang, L.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Huang, Y.

F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
[Crossref] [PubMed]

Huang, Y. L.

F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Jiang, H. B.

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

Jørgensen, C. K.

C. K. Jørgensen, “Electron transfer spectra of lanthanide complexes,” Mol. Phys. 5(3), 271–277 (1962).
[Crossref]

Krupa, J. C.

J. C. Krupa, “Optical excitations in lanthanide and actinide compounds,” J. Alloys Compd. 225(1–2), 1–10 (1995).
[Crossref]

Lebbou, K.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

Li, M. C.

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

Li, T.

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

Liang, H. B.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

Z. J. Wang, P. Wang, J. P. Zhong, H. B. Liang, and J. Wang, “Luminescence properties of lutetium based red emitting phosphor NaLu(WO4)2:Eu3+,” Opt. Mater. Express 3(3), 418–425 (2013).
[Crossref]

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
[Crossref]

Liu, C. G.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

Liu, Y. X.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

McDevitt, N. T.

Moretti, F.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

Nakai, Y.

F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Pan, F. J.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

Seo, H. J.

F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
[Crossref] [PubMed]

Shang, C. Y.

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

Shang, X. H.

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

Su, Q.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
[Crossref]

Su, X. Y.

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

Tao, Y.

F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
[Crossref] [PubMed]

Tsuboi, T.

F. P. Du, Y. Nakai, T. Tsuboi, Y. L. Huang, and H. J. Seo, “Luminescence properties and site occupations of Eu3+ ions doped in double phosphates Ca9R(PO4)7 (R = Al, Lu),” J. Mater. Chem. 21(12), 4669–4678 (2011).
[Crossref]

Wang, J.

Wang, P.

Wang, Q.

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
[Crossref]

Wang, X. J.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

Wang, Y. H.

Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
[Crossref]

Wang, Z. J.

Wang, Z. L.

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
[Crossref]

Wu, S. Q

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Xu, C. S.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

Xu, L. H.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Yan, D. T.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

Yu, H.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Yuan, W.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Zhang, H.

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

Zhang, J. C.

Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
[Crossref]

Zhang, N. M.

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

Zhang, Z. Y.

Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
[Crossref]

Zhao, J.

J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
[Crossref]

Zhao, L. C.

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

Zhao, Q.

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

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H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Zhong, J. P.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
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Z. J. Wang, P. Wang, J. P. Zhong, H. B. Liang, and J. Wang, “Luminescence properties of lutetium based red emitting phosphor NaLu(WO4)2:Eu3+,” Opt. Mater. Express 3(3), 418–425 (2013).
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H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

Zhou, J. B.

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
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H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
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Appl. Spectrosc. (1)

Dalton Trans. (1)

F. Du, R. Zhu, Y. Huang, Y. Tao, and H. J. Seo, “Luminescence and microstructures of Eu3+-doped Ca9LiGd2/3(PO4)7.,” Dalton Trans. 40(43), 11433–11440 (2011).
[Crossref] [PubMed]

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J. Zhao, C. F. Guo, T. Li, X. Y. Su, N. M. Zhang, and J. Y. Chen, “Synthesis, electronic structure and photoluminescence properties of Ba2BiV3O11:Eu3+ red phosphor,” Dyes Pigments 132, 159–166 (2016).
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J. Am. Ceram. Soc. (1)

H. Y. Bian, Y. X. Liu, D. T. Yan, H. C. Zhu, C. G. Liu, C. S. Xu, X. J. Wang, and H. Zhang, “Light-induced electrons suppressed by Eu3+ ions doped in Ca11.94-xSrxAl14O33 caged phosphors for LED and FEDs,” J. Am. Ceram. Soc. 100(8), 3467–3477 (2017).
[Crossref]

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[Crossref]

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[Crossref]

J. Mater. Chem. C (1)

H. Yu, D. G. Deng, D. Zhou, W. Yuan, Q. Zhao, Y. Hua, S. Zhao, L. Huang, L. H. Xu, and S. Q Wu, “Ba2Ca(PO4)2:Eu2+ emission-tunable phosphor for solid-state lighting: luminescent properties and application as white light emitting diodes,” J. Mater. Chem. C 1, 5577–5582 (2013).
[Crossref]

J. Phys. Chem. C (1)

C. Y. Shang, H. B. Jiang, X. H. Shang, M. C. Li, and L. C. Zhao, “Investigation on the luminescence improvement of nanosized La2O3/Eu3+ phosphor under charge-transfer excitation,” J. Phys. Chem. C 115(6), 2630–2635 (2011).
[Crossref]

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Z. Y. Zhang, Y. H. Wang, J. C. Zhang, and Y. Hao, “Luminescent properties of Na3YSi3O9 doped with Eu3+ under UV-VUV excitation,” Mater. Res. Bull. 43(4), 926–931 (2008).
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Opt. Mater. Express (1)

Phys. Status Solidi. A. (1)

Z. L. Wang, H. B. Liang, Q. Wang, M. H. Gong, and Q. Su, “Novel red phosphor of Eu3+, Bi3+ coactivated double tungstates,” Phys. Status Solidi. A. 206(7), 1589–1593 (2009).
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RSC Advances (1)

J. B. Zhou, F. J. Pan, J. P. Zhong, H. B. Liang, Q. Su, F. Moretti, K. Lebbou, and C. Dujardin, “Luminescence properties of Na3LuSi3O9:Ce3+ as a potential scintillator material,” RSC Advances 5(124), 102477 (2015).
[Crossref]

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Figures (6)

Fig. 1
Fig. 1 XRD patterns of Na3Lu0.70Eu0.30Si3O9 (b), Na3Lu0.20Eu0.80Si3O9 (c) and standard card of Na3YSi3O9 (a).
Fig. 2
Fig. 2 Excitation spectra of Na3Lu1-xEuxSi3O9 at room temperature (λem = 611 nm).
Fig. 3
Fig. 3 Emission spectra of Na3Lu1-xEuxSi3O9 at room temperature (λex = 393 nm). The inset shows concentration dependence on the luminescence intensity of Na3Lu1-xEuxSi3O9.
Fig. 4
Fig. 4 Decay curves of (A) Na3Lu1-xEuxSi3O9 (x = 0.10, 0.30, 0.50, 0.80), (B) Na3Lu0.90Eu0.10Si3O9 fitted with second exponential equation.
Fig. 5
Fig. 5 Emission spectra of Na3Lu1-xEuxSi3O9 (x = 0.001, 0.10, 0.20, 0.80) at room temperature (λex = 393 nm).
Fig. 6
Fig. 6 Normalized CTB excitation spectra of (A) Na3Lu0.99Eu0.01Si3O9em = 577 nm, 579 nm), (B) Na3Lu1-xEuxSi3O9em = 579 nm), (C) Na3Lu1-xEuxSi3O9em = 577 nm), (D) Na3Lu0.99Eu0.01Si3O9em = 608 nm, 611 nm, 615 nm, 618 nm, 621 nm, 625 nm).

Tables (1)

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Table 1 Lu3+ sites and Lu–O bond lengths in Na3LuSi3O9

Equations (1)

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I t = A 1 exp ( t / τ 1 ) + A 2 exp ( t / τ 2 )

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